One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,4)(5,6)(7,8)(9,10,14,12)(11,16,13,15)(17,18)(19,21)(20,24)(22,23)(25,29)(26,28)(27,30)(31,32)(1,3,5,8)(2,4,6,7)(9,11,14,13)(10,15,12,16)(20,27)(24,30)(26,31)(28,32)(2,6)(3,8)(9,11,14,13)(10,16,12,15)(18,23)(19,25)(24,30)(26,31)(1,3)(2,7)(4,6)(5,8)(9,10,14,12)(11,16,13,15)(17,19,22,25)(18,21,23,29)(20,26,27,31)(24,28,30,32)(1,3)(2,4)(5,8)(6,7)(9,12,14,10)(11,16,13,15)(17,20)(18,24)(19,26)(21,28)(22,27)(23,30)(25,31)(29,32)(1,4)(2,8)(3,6)(5,7)(9,13,14,11)(10,15,12,16)(17,21)(18,25)(19,23)(20,28)(22,29)(24,31)(26,30)(27,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.