One vertex per element, one color per generator, with an edge from x to x·s.
(2,4)(6,7)(9,10)(11,16)(12,15)(13,14)(17,18,20,22)(19,23,24,21)(25,26)(27,30)(28,29)(31,32)(1,2,5,4)(3,6,8,7)(9,10,14,13)(11,15,12,16)(19,24)(21,23)(25,27,29,32)(26,30,28,31)(2,4)(6,7)(9,11,14,12)(10,15,13,16)(17,18)(19,21)(20,22)(23,24)(25,28,29,26)(27,30,32,31)(1,3,5,8)(2,6,4,7)(9,12,14,11)(10,15,13,16)(17,19)(18,21)(20,24)(22,23)(25,27)(26,31)(28,30)(29,32)(1,4,5,2)(3,7,8,6)(9,13,14,10)(11,15,12,16)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.