One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,6,8,7)(10,12)(15,16)(18,21)(19,23)(25,26,28,30)(27,31,32,29)(2,4)(6,7)(9,10,14,12)(11,15,13,16)(27,32)(29,31)(1,2,5,4)(3,7,8,6)(9,11,14,13)(10,15,12,16)(17,18,20,21)(19,22,23,24)(25,27,28,32)(26,29,30,31)(1,3,5,8)(2,6,4,7)(9,12,14,10)(11,15,13,16)(1,4,5,2)(3,7,8,6)(9,13,14,11)(10,15,12,16)(17,19)(18,22)(20,23)(21,24)(25,26)(27,29)(28,30)(31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.