One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,7)(4,8)(5,6)(9,10,13,12)(11,15,16,14)(17,18)(19,24)(20,23)(21,22)(25,26,29,32)(27,30,31,28)(1,3)(2,4)(5,8)(6,7)(17,19,22,20)(18,23,21,24)(25,27,29,31)(26,30,32,28)(2,6)(3,8)(9,11)(10,14)(12,15)(13,16)(17,18,22,21)(19,23,20,24)(25,26)(27,30)(28,31)(29,32)(1,3)(2,7)(4,6)(5,8)(9,12,13,10)(11,15,16,14)(17,20,22,19)(18,23,21,24)(25,28,29,30)(26,31,32,27)(1,4,5,7)(2,3,6,8)(9,11)(10,14)(12,15)(13,16)(17,21,22,18)(19,23,20,24)(25,26)(27,30)(28,31)(29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.