One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,4)(5,6)(7,8)(9,10)(11,16)(12,15)(13,14)(19,24)(21,23)(25,26,29,28)(27,30,31,32)(2,6)(4,7)(9,11,14,12)(10,15,13,16)(17,18,22,20)(19,23,24,21)(27,31)(30,32)(1,3,5,8)(2,4,6,7)(9,10,14,13)(11,15,12,16)(17,19,22,24)(18,23,20,21)(25,27,29,31)(26,30,28,32)(1,3)(2,7)(4,6)(5,8)(9,12,14,11)(10,15,13,16)(17,20,22,18)(19,21,24,23)(1,4,5,7)(2,3,6,8)(9,13,14,10)(11,15,12,16)(17,21)(18,19)(20,24)(22,23)(25,28,29,26)(27,32,31,30)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.