One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,6)(3,4,8,7)(11,16)(12,14)(18,22)(20,23)(25,26,29,31)(27,28,30,32)(2,6)(4,7)(9,10,13,15)(11,14,16,12)(25,27)(26,28)(29,30)(31,32)(1,3,5,8)(2,7,6,4)(9,11)(10,14)(12,15)(13,16)(17,18)(19,23)(20,24)(21,22)(25,28)(26,30)(27,31)(29,32)(1,3)(2,4)(5,8)(6,7)(9,11)(10,14)(12,15)(13,16)(17,19,21,24)(18,23,22,20)(1,4)(2,3)(5,7)(6,8)(9,12,13,14)(10,11,15,16)(17,20,21,23)(18,24,22,19)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.