One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,7,10,6,11,5,12)(3,13,17,23,16,24,15,8)(4,9,20,26,21,27,19,28)(14,25,18,31,30,32,29,22)(33,34)(35,44,47,40)(36,48)(37,52)(38,43)(39,42)(41,50)(45,62,64,58)(46,56,53,57)(49,55,63,61)(51,60)(54,59)(1,3,7,17,6,16,5,15)(2,8,12,24,11,23,10,13)(4,18,19,14,21,29,20,30)(9,25,26,31,27,32,28,22)(33,35,37,46,39,47,38,53)(34,40,52,57,42,44,43,56)(36,49,50,45,51,63,54,64)(41,58,60,55,59,62,48,61)(1,4,5,19,6,21,7,20)(2,9,10,26,11,27,12,28)(3,14,15,29,16,30,17,18)(8,22,13,25,23,31,24,32)(33,36)(34,41,42,59)(35,45)(37,50)(38,54)(39,51)(40,55,44,61)(43,48,52,60)(46,63)(47,64)(49,53)(56,58,57,62)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.