One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,11,7,10,5,21)(3,12,14,24,16,8,15,25)(4,17,20,9,19,27,22,28)(13,26,18,23,30,32,31,29)(33,34)(35,39,44,54)(36,46,48,61)(37,42)(38,41)(40,47,56,63)(43,58)(45,53,49,57)(50,51)(52,62)(55,60)(59,64)(1,3,5,14,7,16,6,15)(2,8,21,25,10,12,11,24)(4,18,22,30,19,31,20,13)(9,26,17,23,28,32,27,29)(33,35,37,49,38,44,50,45)(34,39,51,53,41,54,42,57)(36,43,47,62,48,59,63,60)(40,55,61,64,56,52,46,58)(1,4,5,22,7,19,6,20)(2,9,21,17,10,28,11,27)(3,13,14,18,16,30,15,31)(8,23,25,32,12,29,24,26)(33,36,37,47,38,48,50,63)(34,40,51,61,41,56,42,46)(35,43,49,62,44,59,45,60)(39,52,53,58,54,55,57,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.