One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,7,8,6)(10,11)(12,16)(17,18,22,24)(19,20,21,23)(27,30)(28,32)(1,3)(2,6)(4,7)(5,8)(17,19,22,21)(18,23,24,20)(25,26,29,31)(27,28,30,32)(9,10,13,11)(12,14,16,15)(17,20)(18,21)(19,24)(22,23)(25,27,29,30)(26,28,31,32)(1,3)(2,7)(4,6)(5,8)(9,11,13,10)(12,15,16,14)(17,20)(18,19)(21,24)(22,23)(1,4,5,2)(3,7,8,6)(9,12)(10,14)(11,15)(13,16)(17,21,22,19)(18,23,24,20)(25,28)(26,30)(27,31)(29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.