One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,6)(3,5,8,7)(9,10,14,16)(11,12,13,15)(18,21)(22,24)(25,26,28,30)(27,31,32,29)(1,2)(3,5)(4,6)(7,8)(9,11,14,13)(10,15,16,12)(9,12)(10,13)(11,16)(14,15)(17,18)(19,22)(20,21)(23,24)(25,27,28,32)(26,29,30,31)(1,2)(3,7)(4,6)(5,8)(9,12)(10,11)(13,16)(14,15)(17,19,20,23)(18,22,21,24)(25,26)(27,29)(28,30)(31,32)(1,3)(2,5)(4,8)(6,7)(9,13,14,11)(10,15,16,12)(17,18)(19,22)(20,21)(23,24)(25,26)(27,29)(28,30)(31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.