One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,5)(4,7)(6,8)(9,10,13,16)(11,14,15,12)(18,20)(19,21)(25,26,28,30)(27,31,32,29)(1,3,6,4)(2,7,8,5)(9,11,13,15)(10,14,16,12)(17,18,22,20)(19,23,21,24)(2,8)(3,4)(9,10)(11,14)(12,15)(13,16)(17,19,22,21)(18,23,20,24)(25,26)(27,29)(28,30)(31,32)(1,4,6,3)(2,7,8,5)(9,10)(11,14)(12,15)(13,16)(17,20,22,18)(19,23,21,24)(1,5,6,7)(2,4,8,3)(9,12,13,14)(10,15,16,11)(17,21,22,19)(18,24,20,23)(25,27,28,32)(26,29,30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.