One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,6)(3,5,8,7)(9,10)(11,16)(12,15)(13,14)(18,19)(20,24)(25,26)(27,32)(28,30)(29,31)(1,2)(3,7)(4,6)(5,8)(10,13)(15,16)(17,18,21,19)(20,23,24,22)(25,27)(26,30)(28,29)(31,32)(9,11,14,12)(10,15,13,16)(17,18,21,19)(20,22,24,23)(25,26)(27,32)(28,30)(29,31)(1,2)(3,7)(4,6)(5,8)(9,12,14,11)(10,15,13,16)(17,19,21,18)(20,22,24,23)(25,26)(27,30)(28,32)(29,31)(1,3)(2,5)(4,8)(6,7)(9,13,14,10)(11,16,12,15)(17,20,21,24)(18,22,19,23)(25,28,29,27)(26,30,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.