One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,10)(3,11,14,26)(4,15,18,8)(5,19,21,9)(7,20,23,13)(12,28,16,27)(17,25,32,30)(22,29,24,31)(34,40)(35,44)(36,39)(37,51)(41,55)(42,59)(43,49)(45,57)(46,52)(47,61)(48,62)(50,53)(56,64)(58,60)(1,3,6,14)(2,7,10,23)(4,16,18,12)(5,20,21,13)(8,24,15,22)(9,26,19,11)(17,29,32,31)(25,27,30,28)(33,34,38,43)(35,45,48,56)(36,49,39,40)(37,42,53,59)(41,46,58,47)(44,55,62,60)(50,63,51,54)(52,57,61,64)(1,4,5,17,6,18,21,32)(2,8,9,25,10,15,19,30)(3,12,13,29,14,16,20,31)(7,22,11,27,23,24,26,28)(33,35)(34,41,43,58)(36,47)(37,52)(38,48)(39,46)(40,45,49,56)(42,60,59,55)(44,51)(50,62)(53,61)(54,57,63,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.