One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,10)(3,11,14,26)(4,15,18,8)(5,19,21,9)(7,20,23,13)(12,28,16,27)(17,25,32,30)(22,29,24,31)(33,34,38,42)(35,43,44,61)(36,47,48,64)(37,52,50,41)(39,54,55,45)(40,57,58,51)(46,59,53,62)(49,56,63,60)(1,3,6,14)(2,7,10,23)(4,16,18,12)(5,20,21,13)(8,24,15,22)(9,26,19,11)(17,29,32,31)(25,27,30,28)(36,48)(40,58)(43,61)(45,54)(47,64)(49,63)(51,57)(59,62)(1,4,5,17,6,18,21,32)(2,8,9,25,10,15,19,30)(3,12,13,29,14,16,20,31)(7,22,11,27,23,24,26,28)(33,35,37,53,38,44,50,46)(34,39,41,60,42,55,52,56)(36,49,51,54,48,63,57,45)(40,59,47,61,58,62,64,43)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.