One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,7,8,6)(9,10)(11,12)(13,14)(15,16)(17,18,20,22)(19,23,24,21)(27,31)(28,30)(2,4)(6,7)(9,10,13,14)(11,16,15,12)(19,24)(21,23)(25,26,29,32)(27,28,31,30)(3,8)(6,7)(10,14)(11,15)(17,18)(19,21)(20,22)(23,24)(25,27,29,31)(26,30,32,28)(1,3,5,8)(2,6,4,7)(9,11,13,15)(10,12,14,16)(17,19)(18,21)(20,24)(22,23)(25,26)(27,30)(28,31)(29,32)(1,4,5,2)(3,7,8,6)(9,12)(10,15)(11,14)(13,16)(17,18)(19,21)(20,22)(23,24)(25,28,29,30)(26,31,32,27)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.