One vertex per element, one color per generator, with an edge from x to x·s.
(2,3)(6,7)(9,10,13,12)(11,15,16,14)(17,18)(19,23)(20,21)(22,24)(1,2,5,3)(4,7,8,6)(9,11)(10,14)(12,15)(13,16)(18,20)(19,24)(25,26,28,30)(27,29,31,32)(2,3)(6,7)(9,11,13,16)(10,15,12,14)(17,18,21,20)(19,23,24,22)(25,26)(27,29)(28,30)(31,32)(1,3,5,2)(4,7,8,6)(9,11)(10,15)(12,14)(13,16)(17,19,21,24)(18,22,20,23)(1,4)(2,6)(3,7)(5,8)(9,12,13,10)(11,14,16,15)(17,20,21,18)(19,23,24,22)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.