One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,13)(4,18)(5,10)(6,11)(7,12)(8,15)(9,20)(14,28)(16,24)(17,23)(19,25)(21,26)(22,31)(27,30)(29,32)(33,34)(35,39,45,53)(36,40)(37,48)(38,42)(41,50)(43,51,58,63)(44,59,61,52)(46,56)(47,55)(49,54)(57,64,60,62)(1,3,5,15,7,17,6,16)(2,8,11,13,12,24,10,23)(4,14,20,30,21,31,19,29)(9,22,18,27,25,28,26,32)(33,35)(34,39,42,53)(36,43)(37,44)(38,45)(40,51,55,63)(41,52,48,59)(46,57)(47,58)(49,60)(50,61)(54,62,56,64)(1,4,7,21)(2,9,12,25)(3,14,17,31)(5,20,6,19)(8,22,24,28)(10,26,11,18)(13,27,23,32)(15,30,16,29)(33,36,38,47)(34,40,42,55)(35,43,45,58)(37,49,50,46)(39,51,53,63)(41,56,48,54)(44,60,61,57)(52,64,59,62)(1,5,7,6)(2,10,12,11)(3,15,17,16)(4,19,21,20)(8,23,24,13)(9,18,25,26)(14,29,31,30)(22,27,28,32)(33,37,38,50)(34,41,42,48)(35,44,45,61)(36,46,47,49)(39,52,53,59)(40,54,55,56)(43,57,58,60)(51,62,63,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.