One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,10,7,11,5,21)(3,12,16,23,15,27,14,8)(4,17,20,25,18,9,19,24)(13,26,30,22,28,32,29,31)(33,34)(35,39,45,53)(36,40)(37,48)(38,42)(41,50)(43,51,58,63)(44,59,61,52)(46,56)(47,55)(49,54)(57,64,60,62)(1,3)(2,8,11,23)(4,13)(5,14)(6,16)(7,15)(9,22,17,31)(10,12,21,27)(18,28)(19,29)(20,30)(24,32,25,26)(33,35)(34,39,42,53)(36,43)(37,44)(38,45)(40,51,55,63)(41,52,48,59)(46,57)(47,58)(49,60)(50,61)(54,62,56,64)(1,4,7,18)(2,9,11,17)(3,13,15,28)(5,20,6,19)(8,22,23,31)(10,25,21,24)(12,26,27,32)(14,30,16,29)(33,36,38,47)(34,40,42,55)(35,43,45,58)(37,49,50,46)(39,51,53,63)(41,56,48,54)(44,60,61,57)(52,64,59,62)(4,18)(9,17)(13,28)(19,20)(22,31)(24,25)(26,32)(29,30)(33,37,38,50)(34,41,42,48)(35,44,45,61)(36,46,47,49)(39,52,53,59)(40,54,55,56)(43,57,58,60)(51,62,63,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.