One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,7,13,6,3,9,17)(4,10,20,35,19,14,28,40)(5,15,25,44,24,11,31,39)(8,12,29,30,23,16,32,27)(18,41,47,64,46,33,57,61)(21,36,49,56,45,34,58,48)(22,42,51,63,50,37,54,62)(26,43,55,53,52,38,60,59)(1,3,7,27,6,2,9,30)(4,14,28,56,19,10,20,48)(5,15,25,53,24,11,31,59)(8,16,29,17,23,12,32,13)(18,41,57,62,46,33,47,63)(21,34,58,35,45,36,49,40)(22,42,54,61,50,37,51,64)(26,43,55,44,52,38,60,39)(1,4,8,21)(2,10,12,36)(3,14,16,34)(5,22,26,18)(6,19,23,45)(7,28,29,58)(9,20,32,49)(11,37,38,33)(13,40,30,48)(15,42,43,41)(17,35,27,56)(24,50,52,46)(25,54,55,57)(31,51,60,47)(39,63,59,64)(44,62,53,61)(1,5,23,52)(2,11,16,43)(3,15,12,38)(4,18,45,50)(6,24,8,26)(7,25,32,60)(9,31,29,55)(10,33,34,42)(13,39,27,53)(14,41,36,37)(17,44,30,59)(19,46,21,22)(20,47,58,54)(28,57,49,51)(35,61,48,63)(40,64,56,62)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.