One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,13)(4,18)(5,10)(6,11)(7,12)(8,15)(9,19)(14,28)(16,24)(17,23)(20,25)(21,26)(22,30)(27,29)(31,32)(33,34,38,43,39,42,37,44)(35,45,48,55,49,58,47,40)(36,50,52,41,53,57,51,56)(46,54,61,64,62,63,60,59)(1,3,5,15,7,17,6,16)(2,8,11,13,12,24,10,23)(4,14,19,29,20,30,21,31)(9,22,18,27,26,28,25,32)(33,35)(34,40,42,55)(36,46)(37,47)(38,48)(39,49)(41,54,56,63)(43,45,44,58)(50,59,57,64)(51,60)(52,61)(53,62)(1,4,7,20)(2,9,12,26)(3,14,17,30)(5,19,6,21)(8,22,24,28)(10,25,11,18)(13,27,23,32)(15,29,16,31)(33,36,39,53)(34,41,42,56)(35,46,49,62)(37,52,38,51)(40,54,55,63)(43,50,44,57)(45,59,58,64)(47,61,48,60)(1,5,7,6)(2,10,12,11)(3,15,17,16)(4,19,20,21)(8,23,24,13)(9,25,26,18)(14,29,30,31)(22,32,28,27)(34,42)(40,55)(41,56)(43,44)(45,58)(50,57)(54,63)(59,64)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.