One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,7)(5,8)(9,10,15,16)(11,12,14,13)(18,20)(19,23)(1,3)(2,5)(4,8)(6,7)(9,11,15,14)(10,13,16,12)(19,23)(22,24)(26,29)(30,32)(3,8)(5,6)(9,12,15,13)(10,11,16,14)(17,18,21,20)(19,22,23,24)(25,26,28,29)(27,30,31,32)(1,2)(3,6)(4,7)(5,8)(9,13,15,12)(10,11,16,14)(17,19,21,23)(18,22,20,24)(1,3)(2,6)(4,8)(5,7)(9,14,15,11)(10,12,16,13)(17,20,21,18)(19,24,23,22)(25,27,28,31)(26,30,29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.