One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,4)(5,8)(6,7)(9,10,12,14)(11,13,15,16)(19,23)(20,24)(27,31)(29,32)(1,3)(2,5)(4,6)(7,8)(9,11,12,15)(10,13,14,16)(17,18,21,22)(19,24,23,20)(1,4,7,5)(2,8,6,3)(9,10)(11,13)(12,14)(15,16)(17,19)(18,20)(21,23)(22,24)(25,26,28,30)(27,29,31,32)(1,5,7,4)(2,8,6,3)(9,11)(10,13)(12,15)(14,16)(17,18)(19,20)(21,22)(23,24)(25,27)(26,29)(28,31)(30,32)(1,6,7,2)(3,4,8,5)(9,10)(11,13)(12,14)(15,16)(17,20)(18,19)(21,24)(22,23)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.