One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,8)(4,7)(5,6)(9,10,15,16)(11,13,14,12)(19,23)(20,24)(1,3)(2,4)(5,8)(6,7)(9,11,15,14)(10,12,16,13)(17,18,21,22)(19,24,23,20)(25,26,28,30)(27,29,31,32)(2,5)(3,7)(9,12,15,13)(10,11,16,14)(17,19)(18,20)(21,23)(22,24)(25,26)(27,29)(28,30)(31,32)(1,4,6,8)(2,7,5,3)(9,13,15,12)(10,11,16,14)(17,18)(19,20)(21,22)(23,24)(1,5,6,2)(3,8,7,4)(9,14,15,11)(10,12,16,13)(17,20)(18,19)(21,24)(22,23)(25,27,28,31)(26,29,30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.