One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,7,8,6)(9,10)(11,13)(12,16)(14,15)(17,18)(19,23)(20,22)(21,24)(26,30)(28,32)(1,2)(3,6)(4,5)(7,8)(9,11)(10,12)(13,15)(14,16)(17,19,22,21)(18,23,20,24)(26,30)(27,31)(2,5)(6,7)(9,12,14,13)(10,11,15,16)(17,19,22,21)(18,24,20,23)(25,26)(27,28)(29,30)(31,32)(1,3,4,8)(2,6,5,7)(9,13,14,12)(10,11,15,16)(17,20,22,18)(19,23,21,24)(25,27)(26,28)(29,31)(30,32)(1,2)(3,6)(4,5)(7,8)(9,11)(10,12)(13,15)(14,16)(17,21,22,19)(18,23,20,24)(25,28)(26,27)(29,32)(30,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.