One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,6)(4,5)(7,8)(9,10,14,11,13,15,12,16)(17,18,22,26)(19,27,28,32)(20,25,21,24)(23,30,31,29)(2,5)(3,7)(9,11,14,15,13,16,12,10)(19,28)(23,31)(27,32)(29,30)(10,15)(11,16)(17,19,22,28)(18,23,26,31)(20,29,21,30)(24,27,25,32)(1,3,4,7)(2,6,5,8)(9,12,13,14)(10,11,15,16)(17,20,22,21)(18,24,26,25)(19,29,28,30)(23,27,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.