One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10,15,16)(11,13,14,12)(19,23)(22,24)(27,28)(30,31)(1,2)(3,6)(4,5)(7,8)(9,11,15,14)(10,12,16,13)(25,26,29,32)(27,30,28,31)(2,5)(6,8)(9,12,15,13)(10,11,16,14)(17,18,21,20)(19,22,23,24)(25,27,29,28)(26,30,32,31)(1,3,4,7)(2,6,5,8)(9,13,15,12)(10,11,16,14)(17,19)(18,22)(20,24)(21,23)(25,26)(27,30)(28,31)(29,32)(1,2)(3,6)(4,5)(7,8)(9,14,15,11)(10,12,16,13)(17,20,21,18)(19,24,23,22)(25,28,29,27)(26,31,32,30)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.