One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,7)(3,8,4,6)(9,10,14,16)(11,12,13,15)(17,18,21,24)(19,23,20,22)(25,26)(27,32)(28,29)(30,31)(1,3,5,4)(2,6,7,8)(9,11,14,13)(10,15,16,12)(19,20)(22,23)(25,26,30,31)(27,32,28,29)(3,4)(6,8)(10,16)(11,13)(17,19,21,20)(18,22,24,23)(25,27,30,28)(26,29,31,32)(1,2)(3,8)(4,6)(5,7)(9,12)(10,11)(13,16)(14,15)(17,20,21,19)(18,23,24,22)(25,28,30,27)(26,29,31,32)(1,4,5,3)(2,6,7,8)(9,13,14,11)(10,12,16,15)(17,18)(19,22)(20,23)(21,24)(25,29)(26,27)(28,31)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.