One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,3,4)(9,10)(11,13)(12,15)(14,16)(17,18,23,20)(19,26,22,24)(21,25,29,28)(27,32,30,31)(6,8)(10,11)(14,15)(17,19,23,22)(18,24,20,26)(21,27,29,30)(25,31,28,32)(5,6,7,8)(9,10,13,11)(12,14,16,15)(17,20,23,18)(19,24,22,26)(21,28,29,25)(27,31,30,32)(1,2)(3,4)(9,11,13,10)(12,14,16,15)(17,21)(18,25)(19,27)(20,28)(22,30)(23,29)(24,31)(26,32)(9,12,13,16)(10,14,11,15)(17,22,23,19)(18,24,20,26)(21,27,29,30)(25,32,28,31)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.