One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,3,4)(9,10,12,14)(11,15,16,13)(17,18,21,22)(19,25,26,23)(20,28,30,24)(27,31,29,32)(6,8)(9,10,12,14)(11,13,16,15)(18,22)(19,26)(24,28)(27,29)(5,6,7,8)(9,10)(11,13)(12,14)(15,16)(17,18)(19,23)(20,24)(21,22)(25,26)(27,31)(28,30)(29,32)(1,2)(3,4)(9,10)(11,13)(12,14)(15,16)(17,19,21,26)(18,23,22,25)(20,29,30,27)(24,32,28,31)(9,11,12,16)(10,13,14,15)(17,20)(18,24)(19,27)(21,30)(22,28)(23,31)(25,32)(26,29)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.