One vertex per element, one color per generator, with an edge from x to x·s.
(3,7)(6,8)(9,10,13,16)(11,15,12,14)(17,18,20,22)(19,23,24,21)(25,26,29,31)(27,28,30,32)(1,2,5,4)(3,6,7,8)(11,12)(14,15)(19,24)(21,23)(25,26)(27,28)(29,31)(30,32)(9,11,13,12)(10,14,16,15)(17,18)(19,21)(20,22)(23,24)(25,27,29,30)(26,28,31,32)(1,3)(2,6)(4,8)(5,7)(9,12,13,11)(10,15,16,14)(17,19)(18,21)(20,24)(22,23)(25,28,29,32)(26,30,31,27)(1,4,5,2)(3,8,7,6)(9,10)(11,14)(12,15)(13,16)(17,18)(19,21)(20,22)(23,24)(25,26)(27,28)(29,31)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.