One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,3)(6,8)(9,10)(11,16)(12,14)(13,15)(17,18)(19,24)(20,27)(21,23)(22,29)(25,30)(26,32)(28,31)(2,3)(9,11)(10,14)(12,13)(15,16)(17,19,23,20)(18,24,21,27)(22,26,30,28)(25,31,29,32)(9,10)(11,16)(12,14)(13,15)(17,20,23,19)(18,24,21,27)(22,28,30,26)(25,31,29,32)(2,3)(5,6)(7,8)(9,10)(11,14)(12,16)(13,15)(17,21,23,18)(19,24,20,27)(22,29,30,25)(26,31,28,32)(1,3,4,2)(9,12,13,11)(10,14,15,16)(17,22)(18,25)(19,26)(20,28)(21,29)(23,30)(24,31)(27,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.