One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,4)(3,7,8,6)(9,10)(11,12)(13,16)(14,15)(19,23)(21,24)(25,26,29,30)(27,31,32,28)(2,4)(6,7)(9,11,15,16)(10,13,14,12)(17,18,20,22)(19,21,23,24)(27,32)(28,31)(9,12,15,13)(10,16,14,11)(17,19)(18,21)(20,23)(22,24)(25,27)(26,28)(29,32)(30,31)(1,3,5,8)(2,6,4,7)(9,13,15,12)(10,16,14,11)(17,18)(19,21)(20,22)(23,24)(25,28)(26,27)(29,31)(30,32)(1,4,5,2)(3,6,8,7)(9,14,15,10)(11,13,16,12)(17,19)(18,21)(20,23)(22,24)(25,26)(27,28)(29,30)(31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.