One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,8)(4,6)(5,7)(9,10)(11,13)(12,14)(15,16)(17,18,20,23)(19,25,27,22)(21,24,29,31)(26,30,28,32)(1,3,5,4)(2,6,7,8)(9,11,14,16,15,12,13,10)(17,19)(18,22)(20,27)(21,26)(23,25)(24,32)(28,29)(30,31)(1,4,5,3)(2,6,7,8)(9,12,13,16,15,11,14,10)(18,23)(19,26)(21,29)(22,30)(25,32)(27,28)(2,7)(6,8)(9,12,14,10,15,11,13,16)(18,23)(22,25)(24,31)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.