One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10,12,14)(11,13,15,16)(17,18,20,22)(19,23,24,21)(25,26)(27,32)(28,30)(29,31)(2,5)(3,7)(19,24)(21,23)(25,26,29,31)(27,32,30,28)(2,5)(6,8)(17,18)(19,21)(20,22)(23,24)(25,27,29,30)(26,28,31,32)(1,2)(3,8)(4,5)(6,7)(9,10)(11,13)(12,14)(15,16)(17,19)(18,21)(20,24)(22,23)(25,28,29,32)(26,30,31,27)(1,3)(2,6)(4,7)(5,8)(9,11,12,15)(10,13,14,16)(17,18)(19,21)(20,22)(23,24)(25,26)(27,28)(29,31)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.