One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,5,8)(3,4,7,6)(9,10,12,15)(11,13,16,14)(18,23)(24,31)(25,26)(27,32)(1,3,5,7)(2,6,8,4)(17,18,21,23)(19,27,29,32)(20,26,22,25)(24,30,31,28)(1,4,5,6)(2,7,8,3)(10,13)(11,16)(14,15)(17,19)(18,24)(20,28)(21,29)(22,30)(23,31)(25,27)(26,32)(2,8)(3,7)(10,13)(11,16)(14,15)(17,20,21,22)(18,25,23,26)(19,28,29,30)(24,27,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.