One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,5)(4,6)(7,8)(9,10)(11,13)(12,14)(15,16)(17,18,20,22)(19,23,24,21)(2,3)(6,7)(9,10,12,14)(11,13,15,16)(17,19)(18,21)(20,24)(22,23)(26,29)(30,32)(4,8)(6,7)(11,15)(13,16)(18,22)(21,23)(25,26,28,29)(27,30,31,32)(1,3,5,2)(4,6,8,7)(9,10)(11,16)(12,14)(13,15)(17,19)(18,23)(20,24)(21,22)(1,4)(2,6)(3,7)(5,8)(9,11)(10,13)(12,15)(14,16)(17,18)(19,21)(20,22)(23,24)(25,27,28,31)(26,30,29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.