One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,5)(4,6)(7,8)(9,10,14,11)(12,16,15,13)(18,22)(19,26)(20,23)(24,28)(25,32)(29,31)(1,3,4,7)(2,5,6,8)(9,11,12,16,14,10,15,13)(17,18,23,28,21,24,20,22)(19,25,30,32,26,31,27,29)(2,6)(5,8)(9,12,14,15)(10,13,11,16)(18,24)(22,28)(25,31)(29,32)(9,13,15,10,14,16,12,11)(17,19,20,27,21,26,23,30)(18,25,22,29,24,31,28,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.