One vertex per element, one color per generator, with an edge from x to x·s.
(2,5)(6,7)(9,10,14,12)(11,15,13,16)(27,31)(29,32)(1,2,4,5)(3,7,8,6)(9,11,14,13)(10,15,12,16)(18,21)(22,24)(25,26,28,30)(27,29,31,32)(1,3,4,8)(2,6,5,7)(9,11,14,13)(10,16,12,15)(17,18,20,21)(19,22,23,24)(25,26)(27,29)(28,30)(31,32)(1,2)(3,6)(4,5)(7,8)(9,12,14,10)(11,15,13,16)(17,19,20,23)(18,22,21,24)(25,27)(26,29)(28,31)(30,32)(1,3)(2,7)(4,8)(5,6)(9,13,14,11)(10,15,12,16)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.