One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,5)(3,6,7,8)(9,10)(11,15)(12,13)(14,16)(18,22)(19,24)(25,26)(27,31)(28,30)(29,32)(2,5)(6,8)(9,10,13,12)(11,14,16,15)(17,18,21,22)(19,20,24,23)(25,27,30,29)(26,31,28,32)(3,7)(6,8)(10,12)(14,15)(18,22)(20,23)(25,26,30,28)(27,32,29,31)(1,2)(3,8)(4,5)(6,7)(9,11,13,16)(10,14,12,15)(17,19)(18,23)(20,22)(21,24)(25,28,30,26)(27,31,29,32)(1,3,4,7)(2,6,5,8)(9,12,13,10)(11,14,16,15)(17,20,21,23)(18,24,22,19)(25,29,30,27)(26,31,28,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.