One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,14)(4,19,23,36)(5,24)(6,28)(7,12)(8,13)(9,17)(10,22,37,30)(11,25)(15,41,20,31)(16,45)(18,33)(21,35,52,59)(26,38)(27,54)(29,34)(32,47)(39,44,48,43)(40,46)(42,62,50,60)(49,56,53,51)(55,58)(57,63,61,64)(1,3,6,17,8,18,7,29)(2,9,12,14,13,34,28,33)(4,20,22,44,23,15,30,43)(5,16,25,46,27,47,26,55)(10,31,36,39,37,41,19,48)(11,32,24,40,38,45,54,58)(21,50,51,64,52,42,56,63)(35,57,53,60,59,61,49,62)(1,4,7,30,8,23,6,22)(2,10,12,36,13,37,28,19)(3,15,17,43,18,20,29,44)(5,21,26,56,27,52,25,51)(9,31,33,48,34,41,14,39)(11,35,24,53,38,59,54,49)(16,42,46,63,47,50,55,64)(32,57,58,62,45,61,40,60)(1,5,6,25,8,27,7,26)(2,11,12,24,13,38,28,54)(3,16,17,46,18,47,29,55)(4,21,22,51,23,52,30,56)(9,32,14,40,34,45,33,58)(10,35,36,53,37,59,19,49)(15,42,43,63,20,50,44,64)(31,57,39,60,41,61,48,62)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.