One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,4,6)(3,7,8,5)(10,11)(12,16)(17,18,21,20)(19,23,24,22)(27,31)(29,32)(3,8)(5,7)(9,10,13,11)(12,14,16,15)(25,26,28,30)(27,29,31,32)(1,3)(2,5)(4,8)(6,7)(9,10,13,11)(12,15,16,14)(17,18,21,20)(19,22,24,23)(25,27)(26,29)(28,31)(30,32)(1,3)(2,5)(4,8)(6,7)(9,11,13,10)(12,14,16,15)(17,19,21,24)(18,22,20,23)(25,26)(27,29)(28,30)(31,32)(1,2)(3,5)(4,6)(7,8)(9,12,13,16)(10,14,11,15)(17,20,21,18)(19,23,24,22)(25,27)(26,29)(28,31)(30,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.