One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,8)(4,5)(6,7)(9,10,13,16)(11,14,15,12)(18,20)(22,24)(25,26)(27,31)(28,30)(29,32)(1,3,6,4)(2,5,7,8)(9,10)(11,12)(13,16)(14,15)(19,23)(22,24)(25,27,30,29)(26,31,28,32)(2,7)(5,8)(9,11)(10,14)(12,16)(13,15)(17,18,21,20)(19,22,23,24)(25,27,30,29)(26,32,28,31)(1,4,6,3)(2,8,7,5)(9,11)(10,14)(12,16)(13,15)(17,19,21,23)(18,22,20,24)(25,28,30,26)(27,31,29,32)(1,5,6,8)(2,4,7,3)(9,12,13,14)(10,15,16,11)(17,20,21,18)(19,24,23,22)(25,29,30,27)(26,31,28,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.