One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,4)(5,6)(7,8)(9,10,14,12)(11,13,16,15)(18,21)(19,23)(25,26,29,30)(27,28,31,32)(2,6)(4,7)(9,11,14,16)(10,15,12,13)(19,23)(22,24)(25,27,29,31)(26,28,30,32)(2,6)(4,7)(9,10,14,12)(11,13,16,15)(17,18)(19,22)(20,21)(23,24)(25,28)(26,27)(29,32)(30,31)(1,3,5,8)(2,7,6,4)(9,12,14,10)(11,15,16,13)(17,19)(18,22)(20,23)(21,24)(25,27)(26,28)(29,31)(30,32)(1,4,5,7)(2,3,6,8)(9,13,14,15)(10,11,12,16)(17,18)(19,22)(20,21)(23,24)(25,26)(27,28)(29,30)(31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.