One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,8)(4,5)(6,7)(9,10,14,13)(11,12,16,15)(18,23)(21,24)(25,26,28,30)(27,29,31,32)(1,3,6,4)(2,5,7,8)(9,11,14,16)(10,15,13,12)(17,18,22,23)(19,24,20,21)(27,31)(29,32)(2,7)(5,8)(10,13)(11,16)(17,19,22,20)(18,21,23,24)(25,26)(27,29)(28,30)(31,32)(1,4,6,3)(2,8,7,5)(9,12)(10,11)(13,16)(14,15)(17,20,22,19)(18,24,23,21)(25,27,28,31)(26,29,30,32)(1,5,6,8)(2,4,7,3)(9,13,14,10)(11,15,16,12)(17,21,22,24)(18,20,23,19)(25,26)(27,29)(28,30)(31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.