One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,7,13,8,14,6,12)(3,15,20,9,19,34,18,33)(4,10,23,37,24,38,30,44)(5,11,28,42,29,43,27,41)(16,35,21,53,48,45,52,31)(17,46,25,32,51,39,50,60)(22,36,26,40,54,61,57,64)(47,59,49,62,55,63,56,58)(1,3)(2,9)(4,21)(5,25,29,50)(6,20)(7,18)(8,19)(10,35)(11,39,43,46)(12,34)(13,15)(14,33)(16,23)(17,27,51,28)(22,47,54,55)(24,52)(26,56,57,49)(30,48)(31,37)(32,41,60,42)(36,58,61,62)(38,45)(40,63,64,59)(44,53)(1,4)(2,10)(3,16,19,48)(5,26)(6,30)(7,23)(8,24)(9,31,33,53)(11,40)(12,44)(13,37)(14,38)(15,45,34,35)(17,49,51,56)(18,52,20,21)(22,27)(25,55,50,47)(28,54)(29,57)(32,59,60,63)(36,41)(39,62,46,58)(42,61)(43,64)(1,5,6,27,8,29,7,28)(2,11,12,41,14,43,13,42)(3,17,18,50,19,51,20,25)(4,22,23,26,24,54,30,57)(9,32,15,46,33,60,34,39)(10,36,37,40,38,61,44,64)(16,47,21,49,48,55,52,56)(31,58,35,59,53,62,45,63)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.