One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,5)(3,8,4,7)(9,10,14,12)(11,13,16,15)(17,18,20,22)(19,21,23,24)(25,26,29,32)(27,28,31,30)(1,3,6,4)(2,7,5,8)(9,11,14,16)(10,15,12,13)(19,23)(21,24)(27,31)(28,30)(2,5)(7,8)(11,16)(13,15)(17,18)(19,21)(20,22)(23,24)(25,27,29,31)(26,30,32,28)(1,4,6,3)(2,8,5,7)(9,12,14,10)(11,15,16,13)(17,19)(18,21)(20,23)(22,24)(25,28,29,30)(26,31,32,27)(1,5,6,2)(3,7,4,8)(9,13,14,15)(10,11,12,16)(17,18)(19,21)(20,22)(23,24)(25,26)(27,30)(28,31)(29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.