One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,5)(3,8,4,7)(9,10,14,12)(11,16,13,15)(17,18,20,22)(19,23,24,21)(26,30)(28,32)(1,3,6,4)(2,7,5,8)(9,11)(10,15)(12,16)(13,14)(17,18,20,22)(19,21,24,23)(26,30)(27,31)(2,5)(7,8)(11,13)(15,16)(17,19)(18,21)(20,24)(22,23)(25,26,29,30)(27,28,31,32)(1,4,6,3)(2,8,5,7)(9,12,14,10)(11,15,13,16)(17,18)(19,21)(20,22)(23,24)(25,27,29,31)(26,28,30,32)(1,5,6,2)(3,7,4,8)(9,13,14,11)(10,16,12,15)(17,19)(18,21)(20,24)(22,23)(25,28)(26,31)(27,30)(29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.