One vertex per element, one color per generator, with an edge from x to x·s.
(2,6)(4,7)(9,10,13,14)(11,15,16,12)(17,18,22,21)(19,24,23,20)(1,2,5,6)(3,4,8,7)(11,16)(12,15)(17,19)(18,20)(21,24)(22,23)(26,29)(30,32)(2,6)(4,7)(9,11)(10,12)(13,16)(14,15)(17,20,22,24)(18,23,21,19)(25,26)(27,30)(28,29)(31,32)(1,3,5,8)(2,7,6,4)(9,12)(10,11)(13,15)(14,16)(17,19)(18,20)(21,24)(22,23)(1,4,5,7)(2,3,6,8)(9,10)(11,12)(13,14)(15,16)(17,21,22,18)(19,20,23,24)(25,27,28,31)(26,30,29,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.