One vertex per element, one color per generator, with an edge from x to x·s.
(1,2)(3,4)(6,7)(9,10)(11,15)(12,16)(13,14)(17,18,22,26)(19,23,29,31)(20,25,21,24)(27,30,28,32)(5,6,8,7)(10,14)(15,16)(17,19,22,29)(18,23,26,31)(20,28,21,27)(24,30,25,32)(2,4)(5,7,8,6)(9,11,13,12)(10,15,14,16)(18,24)(19,27)(20,21)(25,26)(28,29)(30,32)(9,12,13,11)(10,15,14,16)(17,20,22,21)(18,24,26,25)(19,28,29,27)(23,30,31,32)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.