One vertex per element, one color per generator, with an edge from x to x·s.
(1,2,6,13,8,14,7,12)(3,15,18,9,19,34,20,35)(4,21,24,38,26,37,25,10)(5,27,29,41,30,40,31,11)(16,44,46,58,22,32,47,42)(17,48,28,39,49,33,50,43)(23,36,54,60,55,61,56,51)(45,59,64,57,52,62,53,63)(1,3,6,18,8,19,7,20)(2,9,12,15,14,35,13,34)(4,22,24,47,26,16,25,46)(5,28,29,49,30,50,31,17)(10,32,37,58,38,44,21,42)(11,39,40,48,41,43,27,33)(23,53,54,45,55,64,56,52)(36,59,51,63,61,62,60,57)(1,4,8,26)(2,10,14,38)(3,16,19,22)(5,23,30,55)(6,25,7,24)(9,32,35,44)(11,36,41,61)(12,21,13,37)(15,42,34,58)(17,45,49,52)(18,47,20,46)(27,51,40,60)(28,53,50,64)(29,56,31,54)(33,57,48,63)(39,62,43,59)(1,5,8,30)(2,11)(3,17,19,49)(4,23,26,55)(6,31,7,29)(9,33)(10,36)(12,27)(13,40)(14,41)(15,43)(16,45,22,52)(18,50,20,28)(21,51)(24,56,25,54)(32,57)(34,39)(35,48)(37,60)(38,61)(42,59)(44,63)(46,53,47,64)(58,62)A Cayley diagram is a choice, not a fact about the group. Another drawing of this group — in a book, or on a different generating set — may look nothing like this one.